When Electrons Don't Move: the surprisingly difficult physics of spin lattices

Chris Hooley

Abstract

The aim of this Forum session is to give a relatively basic and comprehensible tour of the fun-packed world of spin physics. This refers to the kind of theory used to describe many insulators, where motion of charge is suppressed, and the only important remaining interactions are spin-flips on the sites of a crystal lattice.

(If we were to insist on buzz words, we could slyly mention "spintronics" and "parent compounds of the high-Tc superconductors" - but hey, you're not a funding council, right?)

Depending on the size of the spin, the geometry and dimension of the lattice, and whether the effective interaction between spins is ferro- or antiferromagnetic, a whole host of different behaviours can occur. This can all get a bit confusing, so I'll emphasise trying to give you some feeling for how to think about these systems, rather than just listing a massive quantity of examples.

We'll start with the case of two spins, and gradually work up to chains, planes, and 3D lattices, perhaps taking in spin ladders on the way. Then, if there's time, we can think a bit about how fiddling with the geometry changes the conventional picture that emerges from all that.

And, of course, it would be impossible to write an abstract like this without mentioning Bethe, Heisenberg, and Anderson.
Bethe.
Heisenberg.
Anderson.

There - that's got that one off. See you on Friday!

References

BOOKS
-----

J. H. van Vleck, "Theory of Electric and Magnetic Susceptibilities"
(Clarendon, Oxford, 1932).
        For those with an historical bent, have a look at what they
        were doing when quantum mechanics was just getting started!

J. J. Sakurai, "Modern Quantum Mechanics" (Addison-Wesley, 1994).
        For the basic properties of spin operators, and some nice
        discussions of projection operators etc.

A. Auerbach, "Interacting Electrons and Quantum Magnetism"
(Springer-Verlag (New York), 1994).
        The first half of this book provides a good overview of
        techniques used in treating magnetic systems: almost
        everything I mentioned (at least in part one of my two
        Fora) is discussed here.

C. Kittel, "Quantum Theory of Solids" (Wiley and Sons, 1963).
        Includes a good discussion of the RKKY interaction
        between local moments in metals.


PAPERS
------

P. W. Anderson, Phys. Rev. 86, 694 (1952).
        An absolutely beautiful discussion of the nature of
        spontaneous symmetry breaking and spin-wave theory for
        the antiferromagnet - a must read!

T. Holstein and H. Primakoff, Phys. Rev. 58, 1098 (1940).
        The original spin-waves-as-bosons paper.

C. Marshall, Proc. Roy. Soc. 232, 48 (1955).
        Indranil - this is for you!  A good discussion of the
        extent to which the fictitious states (with more than
	2S bosons) spoil the Holstein-Primakoff correspondence
        in the ferro- and antiferromagnetic cases.

F. J. Dyson, Phys. Rev. 102, 1217 (1956).
F. J. Dyson, Phys. Rev. 102, 1230 (1956).
        Spin wave theory for the ferromagnet.

S. D. Reger and A. P. Young, Phys. Rev. B 37, 5978 (1988).
        The first paper, to my knowledge, where the sublattice
        magnetisation for the spin-1/2 Heisenberg AFM on the
        square lattice was calculated.  The result is
        amazingly close to the linearised spin-wave value!

H. Bethe, Z. Phys. 71, 205 (1931).
        This is a beautiful article, though note that it is in
        German!  It is Bethe's exact solution of the spin-1/2
        AFM Heisenberg chain, a mere five years or so after
	quantum mechanics got off the ground.  No long range
        order (this is impossible in 1D, even at zero temperature),
        but it is critical.  See the second part of my Forum
        couplet for more details

References for 27 April


BOOKS
-----

A. Auerbach, "Interacting Electrons and Quantum Magnetism"
(Springer-Verlag (New York), 1994).
	Quite a lot about the one-dimensional spin chain, including
	a discussion of the even/odd effect as one varies the spin, S.
	I think this is the best book to get a physical feel for
	what's going on.

A. Tsvelik, "Quantum Field Theory in Condensed Matter Physics"
(Cambridge University Press, 1995).
	A more technical discussion, but consistently done within the
	path integral approach.  See in particular chapters 15, 18,
	and 27.

A. Gogolin, A. Nersesyan, and A. Tsvelik, "Bosonization and Strongly
Correlated Systems" (Cambridge University Press, 1998).
	And if you thought the last one was technical, this is the
	real stuff!  This is where you go if you want the full
	derivations behind formulas in Tsvelik (1995).  I recommend
	it only if you intend to work in the field, read very
	quickly, or have problems taking things on trust.


PAPERS
------

H. Bethe, Z. Phys. 71, 205 (1931).
	The original "Bethe Ansatz" paper: an exact solution for the
	spin-1/2 Heisenberg AFM chain.  (In German, but still
	downright magnificent.)

des Cloiseaux and Pearson, Phys. Rev. 128, 2131 (1962).
	Excitations of the spin-1/2 Heisenberg AFM chain.  (A mere
	thirty-one years after Bethe's paper - just goes to show that
	an exact solution is usually not simple!)

P. Jordan and E. Wigner, Z. Phys. 47, 631 (1928).
	How to write a spin-1/2 in terms of fermions, in one
	dimension.

S. Coleman, Phys. Rev. D 11, 2088 (1975).
	How to write a fermion as a boson, in one dimension.  This
	is an absolutely beautiful paper, and in my opinion should
	be read by anyone who is faintly interested in the subject
	of quantum statistics.

I. Affleck and F. D. M. Haldane, Phys. Rev. B 36, 5291 (1987).
	More technical information on the even/odd distinction,
	showing that the half-integer-spin chains are gapless
	by various cunning bits of conformal field theory.  Only
	attempt this if you know a bit of CFT already.  (If you
	don't, Tsvelik (1995) - see above - is quite a good brief
	introduction.)  A classic work, but requires a bit of
	effort.