Surface and Interface Science
Physics 627 / Chemistry 541
Fall 2010

Course Supervisor: Prof. R. A. Bartynski

Updated: 20-Oct-2010


Course Announcements:

Problem Set 1  Due Mon. Oct. 04, 2010
Problem Set 1 Solutions

Problem Set 2  Due Mon. Nov. 01, 2010
Problem Set 2 Solutions
 

Midterm Exam Solution

Suggested term paper topics.
I welcome your own suggestions for term paper topics as well.



Information Personnel Lectures Texts Syllabus


Course Information:

The objective of this course is to provide an introduction to the experimental and theoretical aspects of surface and interface science.  The course will be jointly taught by members of several departments in the physical sciences.

The purpose of the course is to acquaint students in physics, chemistry, materials science and electrical engineering with the static and dynamic behavior of clean and adsorbate-covered solid surfaces and interfaces, from both theoretical and experimental points of view.  Topics will include geometrical structure, surface morphology, electronic structure, surface composition, kinetics and dynamics (adsorption, scattering, vibrations, diffusion, desorption), structure and reactivity of surface molecules, non-thermal excitations of surfaces, catalysis and surface reactions.  Surfaces of metals, oxides and semiconductors will be considered, as well as solid-solid and solid-liquid interfaces.  Modern ultrahigh vacuum experimental methods will be discussed:  theoretical basis, experimental aspects, and data interpretation.

This course is a single semester version of what in previous years had been present as a two semester course.  In addition, we have incorporated new material addressing aspects of interface properties and phenomena. Topics include theoretical and experimental aspects of the electronic and geometric structure of surfaces, an introduction to adsorption, desorption and diffusion, surface processes, including atom and ion scattering, dynamical phenomena, and surface reactions, film growth, aspects of semiconductor processing, nanoscience, and heterogeneous catalysis.

The course requirements include 4 or 5 homework assignments, a midterm examination in November, a paper (approx. 12 pages) due at the end of the semester, and an oral presentation based on the paper.


Course Personnel:

Course Supervisor: R.A. Bartynski (Physics)

Additional Faculty:
L.C. Feldman (Physics and Materials Science)  l.c.feldman@rci.rutgers.edu
E. Garfunkel (Chemistry)   egarf@rci.rutgers.edu
D.C. Langreth (Physics)  langreth@physics.rutgers.edu
T. Gustafsson (Physics)  gustaf@physics.rutgers.edu
B.J. Hinch (Chemistry)  hinch@rutchem.rutgers.edu
D. Vanderbilt (Physics) dhv@physics.rutgers.edu
F. Zimmermann (Physics)  fmz@physics.rutgers.edu

In addition, several other faculty members will present lectures in their areas of expertise, including:  P. Batson (Physics/Materials Science), M. Chhowalla (Materials Science), W.  Wu (Physics), Sean Oh (Physics), V. Podzorov (Physics) and P. Moghe (Biomedical Engineering).


LECTURE SCHEDULE

Monday,  Noon - 1:20 PM; SEC 211 
Thursday,  1:40 - 3:00 PM; SEC 218 


TEXT BOOKS

The recommended texts for this book are:

Physics at Surfaces by Andrew Zangwill
(Cambridge U. Press, 1988)

Modern Techniques of Surface Science - Second Edition by D. P. Woodruff and T. A. Delchar
(Cambridge U. Press, 1994)

Other Resource Materials (on reserve in the Physics Library):

"Practical Surface Analysis" Second Edition, Vol 1 (1990) by D. Briggs, M. P. Seah

"Low Energy Electrons and Surface Chemistry", Second Edition (1985) by G. Ertl, J. Kuppers

"Fundamentals of Surface and Thin Film Analysis", L.C. Feldman and J.W. Mayer, North Holland-Elsevier, N.Y. (1986);
translated into Japanese, Kaibundo Publishing (1988); translated into Russian, MIR Publishing (1989).

"Fundamentals of Nanoscale Film Analysis", Terry L. Alford, Leonard C. Feldman, and James W. Mayer, Springer (2007);
translated into Japanese, (2008)

"Surface Science, an Introduction", (1992) by J. B. Hudson

"Metal Surface Electron Physics" (1996) by A. Kiejna, K. F. Wojciechowski

"Surfaces and Interfaces of Solids", Second Edition (1993) by H. Luth

"Introduction to Surface Physics" (1994) by M. Prutton

"Introduction to Surface Chemistry and Catalysis", (1994) by G. A. Somorjai

"Principles of Adsorption and Reaction on Solid Surfaces" (1996) by R. I. Masel

Some interesting web sites are:

www.physics.rutgers.edu/lsm click on "Links"
http://www.fhi-berlin.mpg.de/th/member/hermann_k.html

COURSE OUTLINE

Surface and Interface Science - Fall 2010
Syllabus
Lecture # Date Instructor Lecture Topic
1 Thurs. 2-Sept. RAB Introduction to course: why are surfaces interesting, begin surface thermodynamics and surface structure
- Mon. 6-Sept. - LABOR DAY, NO CLASSES
2 Wed. 8-Sept. RAB Surface Thermodynamics NOTE: MONDAY CLASSES
3 Thurs. 9 Sept. RAB Surface Structure;Two-dimensional Lattices
4 Mon. 13-Sept. TG Intro to electron spectroscopy: Analyzers, electron optics
5 Thurs. 16-Sept. RAB Surface/Film Composition: XPS
6 Mon. 20-Sept. TG Electron mfp, diffraction methods: LEED; RHEED; Scanning probe
7 Thus. 23-Sept PB Microscopy: Principles of SEM,TEM, LEEM   
8 Mon. 27-Sept. JH Adsorption, desorption, diffusion, etc.
9 Thurs. 30-Sept. LF Ion Scattering Methods - RBS (channeling, NRA, ERD)
10 Mon. 4-Oct. LF Ion Scattering II - MEIS (Channeling, Blocking, HighRes RBS)
11 Thurs. 7-Oct. RAB Intro to Electronic Properties
12 Mon. 11-Oct. RAB Physics of Ultrahigh Vacuum
13 Thurs. 14-Oct. DHV Band Structure: Bulk, Film, Surface
14 Mon. 18-Oct. EG Chemist's approach to electronic structure: From bonds and bands
15 Thurs. 21-Oct. RAB Measuring electronic structure: UPS, ARUPS, IPS
16 Mon. 25-Oct. FMZ Photovoltaics    Additional Notes
17 Thurs. 28-Oct RAB Lab Session: X-ray Photoelectron Spectroscopy [Meet in NPL]
18 Mon. 1-Nov. SO Nucleation and growth of nanostructures and films
19 Thurs. 4-Nov. WW Surface Magnetism
20 Mon. 8-Nov. RAB Vibrational Spectroscopy;    
21 Thurs. 11-Nov. RAB Quantum Confinement at surfaces
-- Mon. 15-Nov. RAB NO LECTURE
22 Tues. 16-Nov. RAB 3-HOUR MIDTERM EXAM; 1PM - 4PM; LOCATION TBA
23 Thurs. 18-Nov. RAB Oxide Surfaces
- Mon. 22-Nov. - NOTE: WEDNESDAY CLASSES, NO LECTURE
- Thurs. 26-Nov. - NO CLASS: THANKSGIVING BREAK
24 Mon. 29-Nov. PM Biomaterial Surfaces and Interfaces
25 Thurs. 2-Dec. JH Energy transfer, sticking, atom scattering
26 Mon. 6-Dec. VP Organic semiconductors/photovoltaics
27 Thurs. 9-Dec. MC Carbon Nanotubes and graphene
28 Mon. 13-Dec. RAB Student papers due; oral presentations

RAB = Bartynski PB = Batson LF = Feldman EG = Garfunkel TG = Gustafsson JH = Hinch
DV = Vanderbilt FZ = Zimmermann MC = Chhowalla SO = Oh VP = Podzorov WW = Wu