Surface and Interface Science
Physics 627 / Chemistry 541
Fall 2008

Course Supervisor: Prof. R. A. Bartynski

Updated: 21-Oct-2008


Course Announcements:

REMINDER: Term paper and your 10 min in-class presentaiton are due Tues, 12/9/2008.

Problem Set 1  Due Tues. Sept. 23, 2008 Problem Set 1 Solutions
Problem Set 2  Due Tues. Oct. 7, 2008 Problem Set 2 Solutions
 
Problem Set 3  Due Tues. Oct. 31, 2008 Problem Set 3 Solutions
 
Midterm Exam Solution

Suggested term paper topics.
I welcome your own suggestions for term paper topics as well.


Information Personnel Lectures Texts Syllabus


Course Information:

The objective of this course is to provide an introduction to the experimental and theoretical aspects of surface and interface science.  The course will be jointly taught by members of several departments in the physical sciences.

The purpose of the course is to acquaint students in physics, chemistry, materials science and electrical engineering with the static and dynamic behavior of clean and adsorbate-covered solid surfaces and interfaces, from both theoretical and experimental points of view.  Topics will include geometrical structure, surface morphology, electronic structure, surface composition, kinetics and dynamics (adsorption, scattering, vibrations, diffusion, desorption), structure and reactivity of surface molecules, non-thermal excitations of surfaces, catalysis and surface reactions.  Surfaces of metals, oxides and semiconductors will be considered, as well as solid-solid and solid-liquid interfaces.  Modern ultrahigh vacuum experimental methods will be discussed:  theoretical basis, experimental aspects, and data interpretation.

This course is a single semester version of what in previous years had been present as a two semester course.  In addition, we have incorporated new material addressing aspects of interface properties and phenomena. Topics include theoretical and experimental aspects of the electronic and geometric structure of surfaces, an introduction to adsorption, desorption and diffusion, surface processes, including atom and ion scattering, dynamical phenomena, and surface reactions, film growth, aspects of semiconductor processing, nanoscience, and heterogeneous catalysis.

The course requirements include 4 or 5 homework assignments, a midterm examination in November, a paper (approx. 12 pages) due at the end of the semester, and an oral presentation based on the paper.


Course Personnel:

Course Supervisor: R.A. Bartynski (Physics)

Additional Faculty:
L.C. Feldman (Physics and Materials Science)  l.c.feldman@rci.rutgers.edu
E. Garfunkel (Chemistry)   egarf@rci.rutgers.edu
D.C. Langreth (Physics)  langreth@physics.rutgers.edu
K. Rabe (Physics)  rabe@physics.rutgers.edu
T. Gustafsson (Physics)  gustaf@physics.rutgers.edu
B J Hinch (Chemistry)  hinch@rutchem.rutgers.edu
F. Zimmermann (Physics)  fmz@physics.rutgers.edu

In addition, several other faculty members will present lectures in their areas of expertise, including:  M. Chhowalla (Materials Science), W.  Wu (Physics), Sean Oh (Physics), V. Podzorov (Physics) and P. Moghe (Biomedical Engineering).


LECTURE SCHEDULE

ARC 108 
Tuesday,  Noon - 1:20 PM
Friday,  Noon - 1:20 PM



TEXT BOOKS

The recommended texts for this book are:

Physics at Surfaces by Andrew Zangwill
(Cambridge U. Press, 1988)

Modern Techniques of Surface Science - Second Edition by D. P. Woodruff and T. A. Delchar
(Cambridge U. Press, 1994)

Other Resource Materials (on reserve in the Physics Library):

Practical Surface Analysis" Second Edition, Vol 1 (1990) by D. Briggs, M. P. Seah

Low Energy Electrons and Surface Chemistry", Second Edition (1985) by G. Ertl, J. Kuppers

Surface Science, an Introduction", (1992) by J. B. Hudson

Metal Surface Electron Physics" (1996) by A. Kiejna, K. F. Wojciechowski

Surfaces and Interfaces of Solids", Second Edition (1993) by H. Luth

Introduction to Surface Physics" (1994) by M. Prutton

Introduction to Surface Chemistry and Catalysis", (1994) by G. A. Somorjai

Principles of Adsorption and Reaction on Solid Surfaces" (1996) by R. I. Masel

Some interesting web sites are:

www.physics.rutgers.edu/lsm click on "Links"
http://www.fhi-berlin.mpg.de/th/member/hermann_k.html

COURSE OUTLINE


Surface and Interface Science - Fall 2008
Syllabus
Lecture # Date Instructor Lecture Topic
1 Tue. - 2-Sept. RAB Introduction to course: why are surfaces interesting, begin surface thermodynamics and surface structure
2 Fri. 5-Sept. RAB Surface Thermodynamics
3 Tue. 9 Sept. RAB Surface Structure; Two-dimensional Lattices
4 Fri.- 12-Sept. TG Electron mfp, diffraction methods: LEED; RHEED; Scanning probe
5 Tue. 16-Sept. FC Microscopy: Principles of SEM, TEM, LEEM    part 1    part 2
6 Fri. 19 Sept. LF Intro to electron spectroscopy: Analyzers, electron optics
7 Tues. 23-Sept RAB Surface/Film Composition: XPS
8 Fri. 26-Sept. LF Ion Scattering Methods - RBS (channeling, NRA, ERD)[SEE NOTES FROM LECTURE 6]
9 Tues. 30-Sept. TG Ion Scattering II - MEIS (Channeling, Blocking, HighRes RBS)
Lecture 9(a)    Lecture 9(b)    Lecture 9(c)
10 Fri. 3-Oct. JH Adsorption, desorption, diffusion, etc.
11 Tues. 7-Oct. RAB Intro to Electronic Properties
12 Fri. 10-Oct DCL Electronic properties of surfaces, jellium, surface band structure, surface states
13 Tues. 14-Oct. RAB Measuring electronic structure: UPS, ARUPS, IPS
14 Fri. 17-Oct. EG Chemist's approach to electronic structure: From bonds and bands
15 Tues. 21-Oct. KR Band Structure: Bulk, Film, Surface [AVS]    Lecture 15(a)    Lecture 15(b)
16 Fri. 24-Oct. FMZ Photovoltaics    Additional Notes [AVS]
17 Tues. 28-Oct. RAB Physics of Ultrahigh Vacuum
18 Fri. 31-Oct. SO Nucleation and growth of nanostructures and films
19 Tues. 4-Nov. RAB Vibrational Spectroscopy;     Group Theory;    HREELS Theory
20 Fri. 7-Nov. WW Surface Magnetism
21 Tues. 11-Nov. RAB Quantum Confinement
22 Fri. 14-Nov. RAB 3-Hour Exam
23 Tues. 18 Nov. RAB Oxide Surfaces
24 Fri. 21-Nov. MC Carbon Nanotubes and graphine
25 Wed. 26-Nov. EG Energy transfer, sticking, atom scattering  NOTE: FRIDAY CLASSES
26 Fri. 28-Nov. --- NO CLASS: THANKSGIVING BREAK
27 Tues. 2-Dec. VP Organic semiconductors/photovoltaics
28 Fri. 5-Dec. PM Biomaterial Surfaces and Interfaces
29 Tues. 9-Dec. RAB Student papers due; oral presentations.

RAB = Bartynski LF = Feldman EG = Garfunkel TG = Gustafsson JH = Hinch DL = Langreth
KR = Rabe FZ = Zimmermann MC = Chhowalla SO = Oh VP = Podzorov WW = Wu